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81.
Methyl-galactosides were oxidized at room temperature by galactose oxidase in a one-step reaction and afforded methyl-galactoaldehyde in excellent yield and high purity. The resulting galactoaldehyde as a useful intermediate can be directly used in glycopeptide synthesis.  相似文献   
82.
A formula for the thickness of a shear band formed in saturated soils under a simple shear or a combined stress state has been proposed. It is shown that the shear band thickness is dependent on the pore pressure properties of the material and the dilatancy rate, but is independent of the details of the combined stress state. This is in accordance with some separate experimental observations. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
83.
All gravity field functionals obtained from an Earth gravitational model (EGM) depend on the underlying terrestrial reference frame (TRF), with respect to which the EGM’s spherical harmonic coefficients refer to. In order to maintain a coherent framework for the comparison of current and future EGMs, it is thus important to investigate the consistency of their inherent TRFs, especially when their use is intended for high precision studies. Following the methodology described in an earlier paper by Kleusberg (1980), the similarity transformation parameters between the associated reference frames for several EGMs (including the most recent CHAMP/GRACE models at the time of writing this paper) are estimated in the present study. Specifically, the differences between the spherical harmonic coefficients for various pairs of EGMs are parameterized through a 3D-similarity spatial transformation model that relates their underlying TRFs. From the least-squares adjustment of such a parametric model, the origin, orientation and scale stability between the EGMs’ reference frames can be identified by estimating their corresponding translation, rotation and scale factor parameters. Various aspects of the estimation procedure and its results are highlighted in the paper, including data weighting schemes, the sensitivity of the results with respect to the selected harmonic spectral band, the correlation structure and precision level of the estimated transformation parameters, the effect of the estimated differences of the EGMs’ reference frames on their height anomaly signal, and the overall feasibility of Kleusberg’s formulae for the assessment of TRF inconsistencies among global geopotential models.  相似文献   
84.
A reliable and accurate gradiometer calibration is essential for the scientific return of the gravity field and steady-state ocean circulation explorer (GOCE) mission. This paper describes a new method for external calibration of the GOCE gradiometer accelerations. A global gravity field model in combination with star sensor quaternions is used to compute reference differential accelerations, which may be used to estimate various combinations of gradiometer scale factors, internal gradiometer misalignments and misalignments between star sensor and gradiometer. In many aspects, the new method is complementary to the GOCE in-flight calibration. In contrast to the in-flight calibration, which requires a satellite-shaking phase, the new method uses data from the nominal measurement phases. The results of a simulation study show that gradiometer scale factors can be estimated on a weekly basis with accuracies better than 2 × 10−3 for the ultrasensitive and 10−2 for the less sensitive axes, which is compatible with the requirements of the gravity gradient error. Based on a 58-day data set, scale factors are found that can reduce the errors of the in-flight-calibrated measurements. The elements of the complete inverse calibration matrix, representing both the internal gradiometer misalignments and scale factors, can be estimated with accuracies in general better than 10−3.  相似文献   
85.
GIS支持下长江口南支河道百年来的演变   总被引:2,自引:0,他引:2  
利用长江口南支河道1900—2001年的5幅海图资料,在GIS的支持下,建立了百年来长江口南支河道的水下数字高程模型(DEM),在此基础上对其演变特征进行了计算和分析。结果表明:(1)1900—2001年间南支河道表现为微冲,不同时段的冲淤状况不同。(2)南支河道的冲淤演变主要表现为5个水道和4个成形沙体的冲淤变化,各水道的最大水深和成形沙体的总面积和总体积都呈不断增大趋势。(3)南支河道各主要断面以复式河槽为主,主槽位于南岸,且最大水深不断增大。位于南支河道入口处和出口处断面的变化比中段断面的变化剧烈。(4)南支河道的演变是自然演变和人工控制共同作用的结果。  相似文献   
86.
87.
The Relation between the Amplitude and the Period of Solar Cycles   总被引:3,自引:0,他引:3  
The maximum amplitudes of solar activity cycles are found to be well anti-correlated (r = -0.72) with the newly defined solar cycle lengths three cycles before (at lag -3) in 13-month running mean sunspot numbers during the past 190 years. This result could be used for predicting the maximum sunspot numbers. The amplitudes of Cycles 24 and 25 are estimated to be 149.5±27.6 and 144.3±27.6, respectively.  相似文献   
88.
AGGLOMERATION AND RADIATION EFFECT OF THE PULL OF URBANIZATION   总被引:2,自引:1,他引:1  
In order to explore the train of thought for China‘s urbanizing development and coordinated rural eco-nomic development, and to find good ways of solving rural problems through urbanization, this paper absorbs the push-and-pull forces theory and the systematic dynamic theory in the traditional population migration theories, views urbanization as a dynamic system, makes research on the push-and-pull mechanism of urbanization. The pulling power of urbanization is analyzed according to two aspects, the agglomeration effect and the radiation effect of cities. The agglomeration effect provides continuous propelling force for urbanization, and the radiation effect further accelerates the urbanization process by pushing forward the development of rural economy. Of course, the slow de-velopment of urbanization can result in the hindrance to rural economic development.  相似文献   
89.
Using the decimetric (700–1500 MHz) radio spectrometer and the synchronous observational system with high temporal resolution at four frequencies (1420, 2130, 2840 and 4260 MHz) of Yunnan Observatory, two rare events were observed on 2001 June 24 and 1990 July 30. The former was a small radio burst exhibiting pulsations with short periods (about 29, 40 and 100 ms) in the impulsive phase. The latter was a large radio burst, which at 2840 MHz produced radio pulsations with period of about 30 ms. This paper focuses on pulsations with very short periods in the range of 29–40 ms. The mechanism of generation of such pulsations may be modulation of radio radiation by the periodic trains of whistler packets originating in unstable regions of the corona. Alternatively, these pulsations can be attributed to wave-wave non-linear interactions of electrostatic upper hybrid waves driven by beams of precipitating electrons in flaring loops.  相似文献   
90.
Based on the analysis of the development of GIS technology and application,this paper brought forward the concept of GoGIS,namely Cooperative GIS ,CoGIS is GIS facing group-users and supporting human-human interaction,which makes it differ from the former GISs,Then,the characteristics of general Computer Spport Cooperative Work (CSCW)applications and the complexity of Geographic Information Science were analyzed,and the conclusion the CoGIS was not a simple GIS layer on CSCW was reached,Further,this paper gaver the hierarchical architecture of CoGIS,and analyzed the coperative platform in detail from the following:1)basic elements;2) collaboration patterns;3) cooperation control mechanism;4) synchronization mechanism;5) security and 6) group communication and so on.With those,the problems about GIS applications are discussed,such as 1)distributed multi-source GIS information and knowledge sharing platform;2)the fusion and visualization of GIS information;3)virtual reality cooperative modeling;4) dymamic simulation;5)expert system and 6) decision-making.Finally,this paper analyzed CoGIS application mode in brief.  相似文献   
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